No, Daniel Boone was not at the Battle of the Alamo. The battle took place in 1836, while Boone passed away in 1820. Boone was a renowned American frontiersman and explorer, famous for his early explorations of Kentucky and his role in westward expansion. The Alamo, on the other hand, was a pivotal event in the Texas Revolution, where Texan defenders fought against Mexican forces. Since Boone was no longer alive during the time of the Alamo, he could not have participated in the battle.