When is combustion not oxidation and when is oxidation not combustion?

Combustion is usually thought of as a rapid reaction that produces heat and light, typically involving a fuel and an oxidant, usually oxygen. However, it’s essential to understand that combustion is a specific type of oxidation. In some cases, combustion can occur without being classified as oxidation in the traditional sense, and oxidation can happen without being combustion.

When is combustion not oxidation?

This scenario is rare and more complex, but one possible example is a reaction where a substance burns without reacting with molecular oxygen. For instance, metals can undergo combustion in the presence of certain halogens, like chlorine, producing metal chlorides. Even though heat may be released—similar to combustion—these processes don’t involve oxygen and can sometimes be categorized differently.

When is oxidation not combustion?

Oxidation is a broader term that refers to the loss of electrons by a substance. It is not limited to rapid reactions producing light and heat. An example of oxidation that isn’t combustion is the rusting of iron. Here, iron reacts with oxygen in the moisture of the air over a prolonged period, forming iron oxide. This process is slow, doesn’t release significant heat or light, and thus is not classified as combustion.

In conclusion, while all combustion reactions are indeed oxidation reactions due to electron transfer, not all oxidation reactions are combustion. Understanding the nuances between these terms can help clarify the broader field of chemical reactions.

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