To draw the Lewis structure for XeO4 (Xenon tetroxide), follow these steps:
- Determine the total number of valence electrons:
- Xenon (Xe) is in Group 18, so it has 8 valence electrons.
- Oxygen (O) is in Group 16, so each oxygen atom has 6 valence electrons. Since there are 4 oxygen atoms, the total number of valence electrons from oxygen is 4 × 6 = 24.
- Add the valence electrons from xenon and oxygen: 8 (Xe) + 24 (O) = 32 valence electrons.
- Place the least electronegative atom in the center:
- Xenon is less electronegative than oxygen, so it will be the central atom.
- Connect the central atom to the surrounding atoms with single bonds:
- Draw single bonds from xenon to each of the four oxygen atoms. This uses 4 × 2 = 8 electrons.
- Distribute the remaining electrons:
- Subtract the electrons used in the bonds from the total valence electrons: 32 – 8 = 24 electrons.
- Place the remaining electrons around the oxygen atoms to satisfy the octet rule. Each oxygen atom needs 6 more electrons to complete its octet, so 4 × 6 = 24 electrons are used.
- Check the octet rule for the central atom:
- Xenon has 8 electrons around it (4 from the single bonds), satisfying the octet rule.
- Finalize the Lewis structure:
- Xenon is surrounded by four oxygen atoms, each with a single bond and three lone pairs of electrons.
The final Lewis structure for XeO4 shows xenon in the center with four single bonds to oxygen atoms, and each oxygen atom has three lone pairs of electrons.