To correctly name the compounds Na3P and Al2S3, we must consider the rules of nomenclature for ionic compounds.
1. **Na3P**: This compound comprises sodium (Na) and phosphorus (P). Sodium is an alkali metal and carries a +1 charge, while phosphorus in this compound acts as a phosphide ion with a -3 charge. When naming this compound, we call the metal first, followed by the non-metal with an ‘ide’ suffix. Thus, Na3P is called Sodium Phosphide.
2. **Al2S3**: This compound contains aluminum (Al) and sulfur (S). Aluminum typically has a +3 charge, whilst sulfur forms a sulfide ion with a -2 charge. Again, we name the metal first, followed by the non-metal with the ‘ide’ suffix. Therefore, Al2S3 is named Aluminum Sulfide.
In summary, the correct names for these compounds are Sodium Phosphide for Na3P and Aluminum Sulfide for Al2S3.