To draw the electron dot structure for CHClO (Chloroformyl chloride), we need to follow a few systematic steps:
- Count the total number of valence electrons. In CHClO, carbon (C) has 4 valence electrons, hydrogen (H) has 1, chlorine (Cl) has 7, and oxygen (O) has 6. Adding these together gives us:
- Carbon: 4
- Hydrogen: 1
- Chlorine: 7
- Oxygen: 6
- Determine the central atom. Carbon (C) is usually the central atom because it can form multiple bonds. So, we place carbon in the center.
- Arrange the other atoms around the central atom. We’ll place the hydrogen (H), chlorine (Cl), and oxygen (O) around the carbon, typically in a tetrahedral geometry.
- Create bonds. Connect each of the atoms to the central carbon atom with a single bond initially:
- C-H
- C-Cl
- C-O
- Distribute remaining electrons. We have 12 valence electrons left to distribute. First, place two electrons (one pair) around the oxygen to complete its octet. Then, allocate the remaining 10 electrons to chlorine, which can hold more than 8 electrons:
- Place 3 pairs (6 electrons) on chlorine, completing its octet.
- Now we have 6 electrons left, which can be kept on the oxygen as lone pairs.
- Carbon is bonded to three different atoms (1 to H, 1 to Cl, 1 to O) and is surrounded by 4 electrons, fulfilling its tetravalent nature.
- Oxygen has 2 bonds and 2 lone pairs, and Chlorine has 3 lone pairs and 1 bond.
Total = 4 + 1 + 7 + 6 = 18 valence electrons
This uses 6 of our 18 valence electrons (2 electrons per bond).
The structure now shows:
This gives us the final electron dot structure for CHClO:
H | C - Cl | O: ..
The dots represent the valence electrons around the atoms, depicting the complete electron dot structure accurately.