To draw the Lewis structure for hydrazine (N2H4), we first need to account for the total number of valence electrons.
Nitrogen (N) contributes 5 valence electrons and hydrogen (H) contributes 1 valence electron. Therefore, for N2H4:
2(N) + 4(H) = 2×5 + 4×1 = 10 + 4 = 14 valence electrons.
Next, we’ll place the atoms in a suitable arrangement. A common structure is to put the two nitrogen atoms in the center, bonded to each other, and then attach four hydrogen atoms around them:
N - N
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H H
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H H
Now, we begin allocating the 14 valence electrons. Each single bond (N-H or N-N) accounts for 2 electrons:
There are 6 electrons used for the three N-H bonds and 2 electrons for the N-N bond, totaling 8 electrons:
2(N-H bonds) + 1(N-N bond) = 8 electrons
This leaves us with 6 electrons remaining. To satisfy the octet rule for each nitrogen, we can form a bond between the two nitrogens:
H2N-NH2
Since each N now forms three bonds (one with each H and one with the other N), they have sufficient electrons to satisfy the octet rule. Each N atom shares a pair of electrons with the other N atom, completing the structure.
In summary, the Lewis structure for N2H4 is:
H2N-NH2
This structure indicates that hydrazine consists of a single bond between the two nitrogen atoms, with each nitrogen bonded to two hydrogen atoms.