What is the Lewis Structure of CNO?

The Lewis structure for the CNO molecule (Cyanate ion, OCN) can be represented by drawing the atoms and their valence electrons.

First, let’s identify the total number of valence electrons available for CNO:

  • Carbon (C) has 4 valence electrons.
  • Nitrogen (N) has 5 valence electrons.
  • Oxygen (O) has 6 valence electrons.
  • As an ion, we also add 1 additional electron due to the negative charge.

This gives us a total of 4 + 5 + 6 + 1 = 16 valence electrons to work with.

Next, we can start sketching the structure:

  1. Place Carbon as the central atom, with Nitrogen and Oxygen around it.
  2. Connect C to N and O with single bonds initially. This uses up 4 electrons (2 for each bond).
  3. So far, we have 16 – 4 = 12 electrons left.

Now we need to complete the octets of the surrounding atoms. Start by adding lone pairs:

  • Add 3 lone pairs to Oxygen (6 electrons) to complete its octet.
  • Add 1 lone pair to Nitrogen (2 electrons) to give it a total of 8 electrons.

After that, distribute the remaining electrons to Carbon. After placing these electrons, we can see the structure:

However, Carbon does not complete its octet in this arrangement. So, we form a double bond between Carbon and Nitrogen:

  1. Remove one lone pair from Nitrogen (2 electrons) and use those to form a double bond with Carbon.
  2. Now, Carbon has 8 electrons and the structure appears stable.

Thus, the final Lewis structure looks like this:

– C is double bonded to N
– N is single bonded to O
– O has three lone pairs

This structure effectively illustrates how the atoms are bonded and accounts for the overall negative charge of the ion.

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