The Lewis structure for the hypochlorite ion (ClO–) can be drawn by following a few simple steps:
- Determine the total number of valence electrons: Chlorine has 7 valence electrons and oxygen has 6. Since we have one negative charge, we add one more electron. So, the total is 7 + 6 + 1 = 14 valence electrons.
- Place the atoms: Place the chlorine atom in the center and the oxygen atom connected to it. The usual bonding between chlorine and oxygen involves a single bond initially.
- Draw the bond: Connect chlorine and oxygen with a single bond, which uses 2 electrons from the total. Now we have 14 – 2 = 12 electrons remaining.
- Distribute the remaining electrons: Start by completing the octets for the outer atoms first. Oxygen needs 6 more electrons to complete its octet, so we place 6 electrons (as 3 lone pairs) around the oxygen atom. This consumes 6 electrons, leaving us with 12 – 6 = 6 electrons.
- Distributing remaining electrons: Now, we have 6 electrons left. Place 2 lone pairs (4 electrons) around the chlorine atom, and that uses 4 of the remaining electrons, leaving us with 2 electrons.
- Final adjustments: To accommodate the ion’s charge and stabilize the structure, place a single bond between chlorine and oxygen, as Cl already has 4 or 5 electrons, it can share more to stabilize the form, contributing the remaining electrons as lone pairs or bonds as required.
Thus, the final Lewis structure for ClO– will have chlorine with two lone pairs and a single bond to oxygen, which has three lone pairs. This visually represents the sharing and distribution of electrons that stabilize the ion. You should see a formal charge of -1 distributed across the oxygen atom, maintaining the charge of the hypochlorite ion securely.