What is the Difference Between Enantiomer and Isomer?

Enantiomers and isomers are both terms used in chemistry to describe different types of molecular structures. However, they refer to distinct concepts.

Isomers

Isomers are molecules that have the same molecular formula but different structural arrangements. This means that while they contain the same number of atoms of each element, the way these atoms are connected or arranged in space differs. There are two main types of isomers:

  • Structural Isomers: These isomers have the same molecular formula but differ in the connectivity of their atoms. For example, butane and isobutane are structural isomers.
  • Stereoisomers: These isomers have the same molecular formula and the same connectivity of atoms, but differ in the spatial arrangement of their atoms. Enantiomers are a type of stereoisomer.

Enantiomers

Enantiomers are a specific type of stereoisomer. They are non-superimposable mirror images of each other. This means that if you were to place one enantiomer in front of a mirror, the reflection would look exactly like the other enantiomer, but you couldn’t rotate or move one to make it identical to the other. Enantiomers have identical physical properties, such as melting point and boiling point, but they often differ in how they interact with polarized light and biological systems. For example, one enantiomer of a drug might be effective, while the other could be inactive or even harmful.

In summary, while all enantiomers are isomers, not all isomers are enantiomers. Isomers encompass a broader category that includes both structural isomers and stereoisomers, with enantiomers being a specific type of stereoisomer.

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